Table
| Pos. | Team | G | W | L | D | Score | P | |
| 1. |
 |
Valencia CF | 6 | 3 | 3 | 0 | 10:4 | 12 |
| 2. |
 |
FC Porto | 6 | 3 | 3 | 0 | 7:2 | 12 |
| 3. |
 |
FC Spartak Moscow | 6 | 2 | 1 | 3 | 8:9 | 7 |
| 4. |
 |
Club Brugge KV | 6 | 0 | 1 | 5 | 1:11 | 1 |
Top scores
JONAS (Valencia)
Lucho GONZALEZ (Porto), Roberto SOLDADO (Valencia), Nelson VALDEZ (Valencia), ARI (Spartak)
DANILO (Porto), Joao MOUTINHO (Porto), James RODRIGUEZ (Porto), KLEBER (Porto), Jackson MARTINEZ (Porto), Fernando GAGO (Valencia), Sofiane FEGHOULI (Valencia), Andres GUARDADO (Valencia), Demy DE ZEUW (Spartak), Nicolas PAREJA (Spartak), Evgeni MAKEEV (Spartak), Emmanuel EMENIKE (Spartak), Marek SUCHY (Spartak), Vadis ODJIDJA-OFOE (Brugge)
Alberto COSTA (Valencia /vs. Spartak/)
Games
1.round, 17.September 2012
Brugge 0:1 Porto
Valencia 1:1 Spartak
2.round, 3.October 2012
Spartak 3:1 Brugge
Porto 1:1 Valencia
3.round, 23.October 2012
Porto 2:0 Spartak
Brugge 0:1 Valencia
4.round, 8.November 2012
Valencia 3:0 Brugge
Spartak 0:2 Porto
5.round, 19.November 2012
Spartak 1:3 Valencia
Porto 0:0 Brugge
6.round, 5.December 2012
Valencia 1:1 Porto
Brugge 0:3 Spartak
Cards
| Team | Players |
| PORTO | Christian ATSU, Joao MOUTINHO, Silvestre VARELA, Steven DEFOUR (2), DANILO, Lucho GONZALEZ, Nicolas OTAMENDI, Eliaquim MANGALA |
| SPARTAK | ROMULO, Evgeni MAKEEV (2), Demy DE ZEUW, Nicolas PAREJA, Evgeni MAKEEV, Kirill KOMBAROV, WELLITON, ARI, Rafael CARIOCA, Kim KALLSTROM, Sergei BRYZGALOV, Pavel YAKOVLEV |
| VALENCIA | Adil RAMI, Aly CISSOKHO (2), Ever BANEGA, JONAS, David ALBELDA, Victor RUIZ |
| BRUGGE | Jonathan BLONDEL (2), JORDI Figueras, Michael ALMEBACK (4), Victor VAZQUEZ, Carl HOEFKENS (2), Tom HOGLI, Mohammed TCHITE, Ryan DONK, Lior REFAELOV, Bart BUYSSE, Maxime LESTIENNE, Thomas MEUNIER, Jesper JORGENSEN, Jim LARSEN |
| Team | Players |
| PORTO | |
| SPARTAK | |
| VALENCIA | |
| BRUGGE | Ryan DONK, Michael ALMEBACK |
| Team | Players |
| PORTO | Steven DEFOUR (1/8 LM - 1.game) |
| SPARTAK | Evgeni MAKEEV (5.round) |
| VALENCIA | Aly CISSOKHO (1/8 LM - 1.game) |
| BRUGGE | Ryan DONK (2.round), Michael ALMEBACK (3.,4.round+6.round), Jonatha BLONDEL (5.round), Carl HOEFKENS (6.round) |
